Well, I don't have any personal experience with the synovial fluid injections, but I sure have treated a lot of people that got them.
It seems like the results are close to 60% success. It can be quite painful for the first few days, but then it settles and lasts up to 6 months.
The patients that seem to get poorer results were patients that had a very tight patellar reticanulum (a membrane that covers the knee cap, crosses over to both sides of the knee). A tight retinaculum and even tight quads can put so much pressure on the knee cap that nothing will make it feel better.
My advice: make sure you konw that there is nothing else going on before relying fully on the injection (placement of the knee cap, flexibility of the retinacum and quads, muscle imbalance...). For more information about what can affect your knee cap, read What runner's knee is all about
here